|
|
2-oxoglutarate + L-norleucine <=> L-glutamate + 2-Oxohexanoate
|
2.6.1.39
2-aminoadipate transaminase
2.6.1.42
branched-chain-amino-acid transaminase
2.6.1.48
5-aminovalerate transaminase
2.6.1.67
2-aminohexanoate transaminase
2.6.1.7
kynurenine---oxoglutarate transaminase
|
–
–
–
–
–
|
|
|
BRENDA:
BR47704
KEGG:
R03053
MetaCyc:
2-AMINOHEXANOATE-AMINOTRANSFERASE-RXN
|
|
|
|
2-Oxohexanoate <=> pentanal + CO2
|
4.1.1.1
pyruvate decarboxylase
4.1.1.43
phenylpyruvate decarboxylase
4.1.1.7
benzoylformate decarboxylase
4.1.1.72
branched-chain-2-oxoacid decarboxylase
|
–
–
–
–
|
|
|
BRENDA:
BS1455
SABIO-RK:
10925
|
|
|
|
L-norleucine + H2O + NAD+ <=> 2-Oxohexanoate + NADH + NH3
|
1.4.1.2
glutamate dehydrogenase
1.4.1.20
phenylalanine dehydrogenase
1.4.1.23
valine dehydrogenase (NAD+)
1.4.1.8
valine dehydrogenase (NADP+)
1.4.1.9
leucine dehydrogenase
|
–
–
–
–
–
|
|
|
BRENDA:
BS232338
SABIO-RK:
7282
|
|
|
|
2-hydroxyhexanoate + O2 <=> 2-Oxohexanoate + H2O2
|
1.1.3.15
(S)-2-hydroxy-acid oxidase
|
–
|
|
|
BRENDA:
BS257492
SABIO-RK:
8053
|
|
|
|
L-norleucine + H2O + O2 <=> 2-Oxohexanoate + NH3 + H2O2
|
1.4.3.2
L-amino-acid oxidase
|
–
|
|
|
BRENDA:
BS259003
SABIO-RK:
10011
|
|
|
|
penicillin_G + 2-Oxohexanoate + O2 <=> phenylacetyl-7-aminodeacetoxycephalosporanic_acid + pentanoate + CO2 + H2O
|
1.14.20.1
deacetoxycephalosporin-C synthase
|
–
|
|
|
BRENDA:
BS377484
SABIO-RK:
7155
|
|
|
|
2-Oxohexanoate + NADH <=> 2-hydroxyhexanoate + NAD+
|
1.1.1.272
D-2-hydroxyacid dehydrogenase (NADP+)
1.1.1.28
D-lactate dehydrogenase
1.1.1.337
L-2-hydroxycarboxylate dehydrogenase (NAD+)
1.1.1.345
D-2-hydroxyacid dehydrogenase (NAD+)
|
–
–
–
–
|
|
|
BRENDA:
BS383764
SABIO-RK:
9928
|
|
|
|
D-norleucine + H2O + O2 <=> 2-Oxohexanoate + NH3 + H2O2
|
1.4.3.3
D-amino-acid oxidase
|
–
|
|
|
BRENDA:
BS259041
|
|
|
|
2-aminohexanoate + H2O + O2 <=> 2-Oxohexanoate + NH3 + H2O2
|
1.4.3.2
L-amino-acid oxidase
|
–
|
|
|
BRENDA:
BS363781
|
|
|
|
L-alanine + H2O + O2 <=> 2-Oxohexanoate + NH3 + H2O2
|
1.4.3.2
L-amino-acid oxidase
|
–
|
|
|
BRENDA:
BS440280
|
|
|
|
D-norleucine + H2O + 2,6-dichlorophenolindophenol <=> 2-Oxohexanoate + NH3 + reduced_2,6-dichlorophenolindophenol
|
1.4.99.6
D-arginine dehydrogenase
|
–
|
|
|
BRENDA:
BS260529
|
|
|
|
2-Oxohexanoate + CoA + oxidized_ferredoxin <=> pentanoyl-CoA + CO2 + reduced_ferredoxin
|
1.2.7.7
3-methyl-2-oxobutanoate dehydrogenase (ferredoxin)
|
–
|
|
|
BRENDA:
BS359417
|
|
|
|
2-hydroxyhexanoate + 2,6-dichlorophenolindophenol <=> 2-Oxohexanoate + reduced_2,6-dichlorophenolindophenol
|
1.1.3.15
(S)-2-hydroxy-acid oxidase
|
–
|
|
|
BRENDA:
BS257450
|
|
|
|
(S)-2-hydroxyhexanoate + ferricytochrome_c <=> 2-Oxohexanoate + ferricytochrome_c
|
1.1.2.3
L-lactate dehydrogenase (cytochrome)
|
–
|
|
|
BRENDA:
BS230741
|
|
|
|
2-Oxohexanoate + acetyl-CoA + H2O <=> 2-butylmalate + CoA
|
2.3.3.17
methylthioalkylmalate synthase
|
–
|
|
|
BRENDA:
BS438747
|
|
|
|
L-lysine + 2-Oxohexanoate <=> 2-aminoadipate_6-semialdehyde + 2-aminohexanoate
|
2.6.1.36
L-lysine 6-transaminase
|
–
|
|
|
BRENDA:
BS354066
|
|
|
|
2-hydroxyhexanoate + NADH <=> 2-Oxohexanoate + NADH
|
1.1.99.2
L-2-hydroxyglutarate dehydrogenase
|
–
|
|
|
BRENDA:
BS257810
|
|
|
|
L-kynurenine + 2-Oxohexanoate <=> Kynurenic_acid + 2-aminohexanoate
|
2.6.1.7
kynurenine---oxoglutarate transaminase
|
–
|
|
|
BRENDA:
BS423750
|
|
|
|
L-tyrosine + 2-Oxohexanoate <=> 4-hydroxyphenylpyruvate + L-norleucine
|
2.6.1.5
tyrosine transaminase
|
–
|
|
|
BRENDA:
BS423789
|
|
|
|
2-Oxohexanoate + CoA + NAD+ <=> pentanoyl-CoA + CO2 + NADH
|
1.2.4.1
pyruvate dehydrogenase (acetyl-transferring)
|
–
|
|
|
BRENDA:
BS387167
|
|
|
|
L-norleucine + H2O + NADH + H+ <=> 2-Oxohexanoate + NH3 + NAD+
|
1.4.1.1
alanine dehydrogenase
|
–
|
|
|
BRENDA:
BS441532
|
|
|
|
2-Oxohexanoate + NH3 + NADH <=> 2-aminohexanoate + H2O + NAD+
|
1.4.1.20
phenylalanine dehydrogenase
|
–
|
|
|
BRENDA:
BS232357
|
|
|
|
2-Oxohexanoate + NH3 + NADH <=> 2-aminocaproate + H2O + NAD+
|
1.4.1.1
alanine dehydrogenase
|
–
|
|
|
BRENDA:
BS371695
|
|
|
|
(S)-2-hydroxyhexanoate + NAD+ <=> 2-Oxohexanoate + NADH + H+
|
1.1.1.345
D-2-hydroxyacid dehydrogenase (NAD+)
|
–
|
|
|
BRENDA:
BS423710
|
|
|
|
D-norleucine + H2O + methylene_blue <=> 2-Oxohexanoate + NH3 + reduced_methylene_blue
|
1.4.99.6
D-arginine dehydrogenase
|
–
|
|
|
BRENDA:
BS260547
|
|
|
|
L-leucine + 2-Oxohexanoate <=> 4-methyl-2-oxopentanoate + 2-aminohexanoate
|
2.6.1.42
branched-chain-amino-acid transaminase
|
–
|
|
|
BRENDA:
BS356508
|
|
|
|
L-norleucine + 4-methyl-2-oxopentanoate <=> 2-Oxohexanoate + L-leucine
|
2.6.1.42
branched-chain-amino-acid transaminase
|
–
|
|
|
BRENDA:
BS356569
|
|
|
|
L-isoleucine + 2-Oxohexanoate <=> L-norleucine + 4-methyl-2-oxopentanoate
|
2.6.1.42
branched-chain-amino-acid transaminase
|
–
|
|
|
BRENDA:
BS356529
|
|
|
|
2-Oxohexanoate + methylamine + NADPH <=> N-methyl-2-aminohexanoate + NADP+ + H2O
|
1.5.1.21
1-piperideine-2-carboxylate/1-pyrroline-2-carboxylate reductase (NADPH)
|
–
|
|
|
BRENDA:
BS387840
|
|
|
|
L-valine + 2-Oxohexanoate <=> 2-oxoisovalerate + 2-aminohexanoate
|
2.6.1.42
branched-chain-amino-acid transaminase
|
–
|
|
|
BRENDA:
BS356558
|
|
|
|
pentanal + 2-Oxohexanoate <=> 6-hydroxydecan-5-one + CO2
|
2.2.1.1
transketolase
|
–
|
|
|
BRENDA:
BS456247
|
|
|
|
L-kynurenine + 2-Oxohexanoate <=> Kynurenic_acid + L-norleucine + H2O
|
2.6.1.7
kynurenine---oxoglutarate transaminase
|
–
|
|
|
BRENDA:
BS353508
|
|
|
|
L-tryptophan + 2-Oxohexanoate <=> 3-Indole-2-oxopropanoate + L-norleucine
|
2.6.1.28
tryptophan---phenylpyruvate transaminase
|
–
|
|
|
BRENDA:
BS356429
|
|
|
|
2-oxosuccinamic_acid + L-norleucine <=> L-asparagine + 2-Oxohexanoate
|
2.6.1.14
asparagine---oxo-acid transaminase
|
–
|
|
|
BRENDA:
BS354185
|
|
|
|
L-histidine + 2-Oxohexanoate <=> 3-(1H-imidazol-4-yl)-2-oxopropanoate + L-norleucine
|
2.6.1.38
histidine transaminase
|
–
|
|
|
BRENDA:
BS356483
|
|
|
|
beta-Alanine + 2-Oxohexanoate <=> malonate_semialdehyde + L-norleucine
|
2.6.1.18
beta-alanine---pyruvate transaminase
|
–
|
|
|
BRENDA:
BS353480
|
|
|
|
L-norleucine + H2O + 2 cytochrome_b <=> 2-Oxohexanoate + NH3 + 2 reduced_cytochrome_b
|
1.4.99.B3
|
–
|
|
|
BRENDA:
BS439678
|
|
|
|
(R)-2-hydroxycaproate + acceptor <=> 2-Oxohexanoate + reduced_acceptor
|
1.1.99.6
D-lactate dehydrogenase (acceptor)
|
–
|
|
|
BRENDA:
BS189039
|
|
|
|
2-hydroxyhexanoate + acceptor <=> 2-Oxohexanoate + reduced_acceptor
|
1.1.99.31
(S)-mandelate dehydrogenase
|
–
|
|
|
BRENDA:
BS383758
|
|
|
|
L-norvaline + 2-Oxohexanoate <=> 2-Oxopentanoate + 2-aminohexanoate
|
2.6.1.42
branched-chain-amino-acid transaminase
|
–
|
|
|
BRENDA:
BS437643
|
|
|
|
3-amino-5-methylhexanoate + 2-Oxohexanoate <=> 5-methyl-3-oxohexanoate + 2-aminohexanoate
|
2.6.1.18
beta-alanine---pyruvate transaminase
|
–
|
|
|
BRENDA:
BS436862
|
|
|
|
L-allo-isoleucine + 2-Oxohexanoate <=> 3-methyl-2-oxopentanoate + 2-aminohexanoate
|
2.6.1.42
branched-chain-amino-acid transaminase
|
–
|
|
|
BRENDA:
BS356544
|
|
|
|
L-glutamine + 2-Oxohexanoate <=> 2-Oxoglutaramate + L-norleucine
|
2.6.1.50
glutamine---scyllo-inositol transaminase
2.6.1.64
glutamine---phenylpyruvate transaminase
|
–
–
|
|
|
BRENDA:
BS356695
|
|
|
|
L-alanine + 2-Oxohexanoate <=> pyruvate + 2-aminohexanoate
|
2.6.1.12
alanine---oxo-acid transaminase
|
–
|
|
|
BRENDA:
BS353471
|
|
|
|
pyruvate + L-norleucine <=> L-alanine + 2-Oxohexanoate
|
2.6.1.12
alanine---oxo-acid transaminase
|
–
|
|
|
BRENDA:
BS353458
|
|
|
|
phenylpyruvate + L-norleucine <=> L-phenylalanine + 2-Oxohexanoate
|
2.6.1.28
tryptophan---phenylpyruvate transaminase
2.6.1.64
glutamine---phenylpyruvate transaminase
|
–
–
|
|
|
BRENDA:
BS356446
|
|
|
|
FMN + 2-hydroxyhexanoate <=> 2-Oxohexanoate + FMNH2
|
1.1.99.31
(S)-mandelate dehydrogenase
|
–
|
|
|
SABIO-RK:
6618
|
|
|
|
ampicillin + O2 + 2-Oxohexanoate <=> pentanoate + CO2 + cephalexin + H2O
|
1.14.20.1
deacetoxycephalosporin-C synthase
|
–
|
|
|
SABIO-RK:
7168
|
|